Systematicity, the probabilistic mapping of form to meaning, permeates language at all levels, and sublexical cues have been shown to govern human pseudoword processing.
Yet whether LLMs exhibit comparable sensitivity to these cues remains unclear.
We tested five LLMs on two Italian two-alternative forced-choice pseudoword experiments and compared their responses with a human behavioural baseline.
LLMs aligned more reliably with humans when real-word options provided a lexical familiarity cue than in the pseudoword-only condition, where they fell substantially below fastText, a character-n-gram model.
In addition, the sublexical cosine-similarity cue that reliably drove human--fastText agreement did not consistently transfer to human--LLM alignment, and reasoning-token expenditure bore no consistent relation to human processing difficulty.
These findings suggest that LLMs do not necessarily share the sublexical cues that govern human pseudoword processing; we discuss tokenization and training-data coverage as candidate explanations.